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Beilstein J. Org. Chem. 2013, 9, 664–674, doi:10.3762/bjoc.9.75
Graphical Abstract
Figure 1: The most intensively studied PKS, deoxyerythronolide B synthase (DEBS), which catalyzes the key ste...
Scheme 1: Synthesis of SNAC-activated D3-methylmalonate. a: 2.1 equiv [(CH3)2CH]2NLi, 1 equiv CD3I, abs. THF,...
Figure 2: Structures of erythromycin (left) and rapamycin (right). In this experiment both compounds were lab...
Figure 3: Relative incorporation of the D3-label into erythromycin (A) and rapamycin (B), depending on the fe...
Figure 4: ESI–MS spectra of feeding experiments with an erythromycin-producing culture of S. erythraea. The m...
Scheme 2: Incorporation of a propargylated malonic acid derivative into erythromycin through an active-site m...
Beilstein J. Org. Chem. 2005, 1, No. 10, doi:10.1186/1860-5397-1-10
Scheme 1:
Figure 1: Evolution of conversion of ketone 1 using PAMO mutant P3 with increasing substrate concentration in...
Scheme 2:
Figure 2: Effect of different solvents on the stability of PAMO, measured as residual activity. For cyclohexa...
Scheme 3:
Figure 3: Conversion during the oxidation of ketone 6 in a two-liquid phase system over the time. The catalys...